Synthesis and STM imaging of symmetric and dissymmetric ethynyl-bridged dimers of boron-subphthalocyanine bowl-shaped nanowheels.

نویسندگان

  • Henri-Pierre Jacquot de Rouville
  • Romain Garbage
  • Francisco Ample
  • Anja Nickel
  • Joerg Meyer
  • Francesca Moresco
  • Christian Joachim
  • Gwénaël Rapenne
چکیده

The future's wheel: A new class of wheels, based on subphthalocyanine fragments, for future incorporation in functional nanovehicles is reported (see figure). The syntheses of a symmetric wheel, a nitrogen-tagged wheel, and their ethynyl-bridged homodimers are presented. Theoretical calculations and STM imaging demonstrate the advantage of a bowl-shaped structure and the efficiency of the tag for STM imaging.

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عنوان ژورنال:
  • Chemistry

دوره 18 29  شماره 

صفحات  -

تاریخ انتشار 2012